Howdy Vince, welcome from another GMT400'er
The redesigned (many times) intermediate steering shaft and lower column bearing should cure the clunk, and the A/C service ports are fairly simple to replace.
I did the service ports on my '06 recently as they showed signs of slight leakage although the A/C was still working, I knew it was just a matter of time.
The steering shaft and bearing I did probably 80K miles ago and it's still quiet, so I guess GM finally got it right. Probably about similar miles on my wife's '06 as well. A little bit of a pain contorting yourself under the dash to replace those parts but overall a simple job. Just be sure you secure the steering wheel with a bungee cord, ratchet strap, something so it can't turn while you have the shaft disconnected, because otherwise the clockspring will become damaged. It can move a little, that's fine, you just don't want it making an actual revolution in either direction because then the clockspring isn't in the correct wound position anymore. Anyway, literally a 30 minute job start to finish.
This is replacing it on my wife's truck - old vs. new on both items. My recommendation is GM only for both. The bearing just pushes in at the bottom of the column tube inside the cab; some gentle persuading at the exposed edge with a very small hammer will start it sliding out. I ordered GM # 19329330 shaft (currently about $60) and GM # 88963617 bearing (about $33) - those fit '06 models and probably yours too but double check to be sure.
Bungee cord run from the spoke to the shifter kept the wheel in place.
Replacing the A/C service ports on my truck was a snap, even though I didn't have the oddball socket for the high side, I was able to remove it with an adjustable wrench. It's not super tight or anything, being an aluminum fitting in a thin aluminum tube. I did need to run down to the parts house and get a valve core tool for the low side as a regular tire tool didn't have enough reach. "Xtra Seal" brand # 15-3174 you can see on my core support with the black/orange handle got it done for under $7. The service port kit I used was Four Seasons 26775 which I paid a little extra from amzn to get it here quick, still less than $15. I used some Nylog blue sealant on the threads and o-rings as well.
Richard